Perovskite nanocrystals
Watching electrons at work
![https://3s17.empa.ch/documents/56164/27642074/stopper_perovskite-nanocrystals.jpg/8eb62054-c943-49e0-b697-5637f44aeeaa?t=1701680913000](https://3s17.empa.ch/documents/56164/27642074/stopper_perovskite-nanocrystals.jpg/8eb62054-c943-49e0-b697-5637f44aeeaa?t=1701680913000)
In brief:
- Researchers used extremely short electron pulses to take picosecond-resolution snapshots of the crystal lattice of perovskite nanocrystals while they absorbed photons.
- The electrons excited by the photons were found to straighten out the skewed crystal lattice of the nanocrystals, resulting in the effective attractive interaction between excitons (bound pairs of electrons and holes).
- Understanding the origin of the coupling between excited electrons and vibrations of the crystal lattice will make it possible for researchers to engineer perovskites with particular optical properties.
Many a scientific and technical problem could be solved easily if it were possible to look inside a material and watch its atoms and electrons wiggle about in real time. In the case of halide perovskites, a class of minerals that has become very popular in recent years for their use in technologies ranging from solar cells to quantum technologies, physicists have long tried to understand their excellent optical properties.
A team of researchers led by Nuri Yazdani and Vanessa Wood at ETH Zurich, and Aaron Lindenberg at Stanford, along with colleagues at Empa in Dübendorf, have now made significant progress towards our understanding of perovskites by studying the motion of atoms inside nanocrystals with a time resolution of a few billionths of a second. They recently published their findings in the scientific journal Nature Physics.
“Halide perovskites are great for many opto-electronic applications,” says Yazdani. “But it is in some ways puzzling how this class of materials can exhibit such outstanding optical and electronic properties.” Perovskites are minerals that have the same type of crystal structure as calcium titanate (CaTiO3), the “original” perovskite. Researchers knew that when perovskites absorb light, electrons that are excited to higher energies couple strongly to phonons inside the material. Phonons are collective vibrations, similar to sound waves, of the atoms in a crystal. “Often one can treat the average position of each atom inside a crystal as fixed, but that is no longer possible when an optical excitation of an electron leads to a large reorganisation of the crystal lattice,” Yazdani explains. The question the researchers had to answer was, therefore: how do excited electrons in perovskites change the shape of the crystal lattice?
Looking inside nanocrystals
To take a peek inside a perovskite (formamidinium lead bromide) synthesised at Empa by Maryna Bodnarchuk and Maksym Kovalenko, the researchers used an ultrafast electron diffraction beamline facility at the Stanford National Accelerator Laboratory (SLAC) that produces very short pulses of electrons lasting only a hundred femtoseconds, or millionths of a millionth of a second. These electrons then hit the perovskite nanocrystals, about 10 nanometres in size, and the diffracted electrons are collected on a screen. Since electrons are quantum particles that behave like waves, after being diffracted from the atoms inside the material the electron waves interfere constructively or destructively, depending on the positions of the atoms and the direction of diffraction – much like light emerging from a double slit. Even tiny changes in the crystal structure can be measured in this way.
The ETH researchers made use of a special feature of the SLAC beamline to take snapshots of the crystal structure during and after the absorption of a photon: by using the same laser to create the photons and to trigger the electron pulse, they were able to control the photon’s arrival time at the nanocrystals relative to that of the electrons by changing the distance that the photons had to travel. From the analysis of those snapshots over several hundreds of picoseconds (billionths of second), it was possible to see how the deformation of the crystal lattice caused by the photo-excited electrons evolved over time.
Surprising increase in symmetry
Tailoring the optical properties of perovskites
Prof. Dr. Maksym Kovalenko
Empa – Thin Films and Photovoltaics
Phone +41 58 765 45 57
Dr. Nuri Yazdani
ETH Zurich – Institute for Electronics
Phone +41 44 632 60 91
Anna Ettlin
Communications
Phone +41 58 765 47 33
ETH Zurich – Corporate Communications
Phone +41 44 632 42 44
desk@hk.ethz.ch
Yazdani, N., Bodnarchuk, M.I., Bertolotti, F., Kovalenko, M.V., Wood, V., Lindenberg, A.L. et al. Coupling to octahedral tilts in halide perovskite nanocrystals induces phonon-mediated attractive interactions between excitons. Nat. Phys. (2023). doi: 10.1038/s41567-023-02253-7
Rainò, G., Yazdani, N., Wood, V., Kovalenko M.V., et al. Ultra-Narrow Room-Temperature Emission from Single CsPbBr3 Perovskite Quantum Dots. Nat. Commun. 2022, 13, 2587. doi: 10.1038/s41467-022-30016-0
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